Selective Noncatalytic Reduction of NO<i><sub>x</sub></i> Using Ammonium Sulfate

نویسندگان

چکیده

Ammonium sulfate (AS) is of interest as an additive in stationary combustion plants for the simultaneous control NOx (through selective noncatalytic reduction, SNCR) and deposition corrosion sulfation alkali chlorides). The SNCR performance ammonium was evaluated through experiments a laboratory-scale flow reactor. Experiments with 5 10 wt % aqueous solutions, corresponding to AS/NO ratios above 1, yielded NO reductions up 95% temperature interval 1025–1075 °C. results indicated that sulfur from mainly released SO3, even though SO2 detected increasing concentrations at temperatures 1000 Addition KCl process shown promote reaction lower temperatures, extending window reduction by 50 Furthermore, facilitated high degree or below °C, demonstrating potential using simultaneously reduce full-scale plants. were analyzed terms detailed kinetic model. described satisfactorily model, although optimum slightly underestimated. Also, captured well, but promoting effect on greatly Possible reasons this discrepancy discussed.

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ژورنال

عنوان ژورنال: Energy & Fuels

سال: 2021

ISSN: ['1520-5029', '0887-0624']

DOI: https://doi.org/10.1021/acs.energyfuels.1c01451